2931036 - Not possible to add the same purchasing organization to two different company codes

While trying to assign the Purchasing Organization to the second company code via SSCUI 100066 - Organizational Structure, the following error message is encountered;

"Target ID is used already in another entity of the same type"

"Image/data in this KBA is from SAP internal systems, sample data, or demo systems. Any resemblance to real data is purely coincidental."

SAP S/4HANA Cloud Public Edition

Company code, central, purchasing, organization, target, id,another, entity, of, the, same type, 100066, assign, SAP S/4HANA Cloud Public Edition, S4_PC, SV-CLD-FRM-APP . , KBA , SV-CLD-FRM-APP , Flexorg, Foreign Key Check , MM-PUR-GF-CU , Customizing , Problem