There is not any option to Reject one item in Service order or Service quotation.
SAP S/4HANA all versions
Reject, item, solution quotation , KBA , CRM-S4-SRV-SVQ , S4CRM: Service Order Quotation , CRM-S4-SOL-SQ , S4CRM: Solution Quotation , CRM-S4-SRV-SVO , S4CRM: Service Order , How To
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